Scarlett Johansson is taking the title of Esquire's sexiest woman alive for a second time. The actress, who currently stars in the Joseph Gordon-Levitt comedy "Don Jon" is the first woman to get the honor twice. She first earned the title in 2006. Mila Kunis was awarded the honor last year. Johannson recently announced her engagement to former French journalist Romain Dauriac. It will be her second marriage after splitting from Ryan Reynolds in 2010. Johansson appears on the cover of the November issue of "Esquire," due out October 15th.